Van't Hoff's Factor

IMPORTANT

Van't Hoff's Factor: Overview

This topic covers concepts such as Abnormal Colligative Properties, Van't Hoff's Factor, Van't Hoff Correction Factor for Dissociation of Solute Particles, Determination of Degree of Dissociation Using Van't Hoff's Factor, etc.

Important Questions on Van't Hoff's Factor

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Relative decrease in vapour pressure is 0.4 for a solution containing 1 mole AB in 3 mol H2O, therefore AB is ionised at the extent of

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If the osmotic pressure of a 0.010 M aqueous solution of sucrose at 27oC is 0.25 atm, then the osmotic pressure of a 0.010 M aqueous solution of NaCl at 27oC is

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What are the minimum values of the Van't Hoff factors in a solute undergoing dimerisation and trimerisation?

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Which of the following is the correct value of degree of association α in terms of van't Hoff factor (i) is:

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Which of the following is the correct value of degree of dissociation α in terms of van't Hoff factor (i) is:

MEDIUM
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Integral value of van't hoff factor for K2SO4:

EASY
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Which of the following will show maximum lowering in vapour pressure:

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Ba2+,CN-, And Co2+ form an ionic compound. If the complex is supposed to 75% ionised in water with van't Hoff factor =4, what is the coordination number of Co2+ in the complex?

MEDIUM
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Four solutions of K2SO4 with the concentration 0.1 m, 0.01 m, 0.001 m and 0.0001 m are available. The maximum value of van't Hoff factor, i corresponds to:

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The vapour density of undecomposed N2O4 is 46. When heated, vapour density decreased to 24.5 due to its dissociation to NO2. The percent dissociation of N2O4 at the final temperature is :

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The Van't Hoff's factor for 0.1 M BaNO32 solution is 2.74. The degree of dissociation is:

EASY
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Ba2+,CN-, and Co2+ form an ionic compound. If the complex is supposed to 75% ionized in water with van't Hoff factor =4, what is the coordination number of Co2+ in the complex ?

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The value of Van't Hoff factor (i) for K3Fe(CN)6 is X, if it undergoes 75% dissociation in aqueous medium, calculate 4X?

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The degree of dissociation of an electrolyte is α and its van't Hoff factor is i. The number of ions obtained by complete dissociation of 1 molecule of the electrolyte is:

MEDIUM
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The Van't Hoff factor of solutes A, B and C in aqueous solutions are 0.8, 1.6 and 1.2 respectively. The freezing point of equimolar solutions follow the order :

EASY
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Which one of the following electrolyte has the same value of vant'Hoff factor (i) as that of Al2 (SO4)3 (If 60% ionised) :-

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The vapour density of PCl5 is 104.25 but when heated to 230°C, its vapour density is reduced to 62. The degree of dissociation of PCl5 at this temperature will be:-

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In a 0.2 molal aqueous solution, a weak acid (HX) is 20% ionized. The freezing point of this solution is :-

Kf=1.86 K.m-1

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The molecular weight of NaCl,  determined by studying freezing point depression of its 0.5% aqueous solution is 30. The apparent degree of dissociation of NaCl is:-

MEDIUM
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The value of observed and calculated molecular weight of calcium nitrate are 65 and 164. The degree of dissociation of CaNO32 will be:-